Sillimanite belongs to the rich Alumino - Silicate group of minerals and is a polymorph of Kyanite and Andalusite represented by the chemical formula Al2SiO5. According to Wikipedia this mineral has been named after American chemist Benjamin Silliman (1779 - 1864). Sillimanite is a very important refractory raw material for high alumina refractories which are extensively used in Iron and steel, Petrochemical, Electrical, Cement, Zinc and Glass industries. Read: Use of Sillimanite as Raw Material in Refractories
Now it is not available since the reserves have been depleted. The only other important occurrence is around Pipra in Madhya Pradesh (India) popularly known as Rewa Sillimanite and in Bhandara district of Maharashtra (India). The disadvantage of Rewa sillimanite is that it slightly sensitive to thermal shocks. An authorized supplier of Rewa / Bhandara sillimanite is M/s Pavri Kyanite Mines, Maharashtra. An alternate source is available today from Beach Sand (a by-product of Indian Rare Earths Limited, a Government of India Undertaking under its Department of Atomic Energy). One has to fulfill certain formalities with Indian Rare Earths Limited in order to procure sillimanite sand from them. The beach sand deposits are the potential sources of sillimanite along with rutile, ilmanite, monazite, garnet, zircon and quartz. The Chavara (Kerala, India), Manavalakurichi (Tamil Nadu, India) and Chatrapur (Orissa, India) are among the richest deposits in the world. Indian beach sand deposits contain about 9% rutile, 6% garnet, 3% sillimanite and 1% monazite and zircon. After magnetic removal of Monazite, sillimanite, garnet, zircon and rutile are separated from one another by gravity tabling, electrostatic and flotation techniques. The following table shows the Chemical Composition of Sillimanite of two different sources:
Sillimanite is found as brown, grayish, pale green or white orthorhombic mineral with long slender, needle shaped crystals. Optically, it is subhedral, elongated, colourless and non-pleochroic (or colourless to pale brownish yellow) in plane polarized light. Sillimanite has low r.i., one set cleavage, and straight extinction in grains which are parallel to elongation. In pure form it has specific gravity 3.23 and Moh’s hardness 6 - 7.5.
Sillimanite occurs in fibrous masses mainly in the form of bundles and is characteristic of the innermost zone of contact metamorphosed rocks. Because of this nature of its occurrence this mineral is also known as ‘Fibrolite’.
Massive Sillimanite deposits of the Nongstoin state in the Khasi Hills of Assam (Meghalaya) in India commonly known as Assam Sillimanite, was the world famous for its quality and quantity. The host rocks were Cordierite - Biotite - Quartz - Muscovite - Gneiss or a Sillimanite - Quartz - Schist with intrusions of Granite.