Chemically, fire clay contain mainly silicon and aluminium - or since these elements usually occur as oxides, as silica and alumina - with smaller amounts of iron, calcium, sodium and other elements. In aluminosilicate or fireclay refractory bricks, raw clay is added as a sintering aid or even as a main constituent depending upon its application, while firing temperature is ideally tailored as per the raw materials used.
The two main reasons attributed to the formation of Black Core in fireclay refractory bricks are:
Considering the above mentioned factors, the three steps that should be taken in order to avoid the formation of Black Core in fireclay refractory bricks especially, are:-
How to stop formation of Black Cores (Black Reducing Spots)
Due the fineness of this clay, gas diffusion during firing may be inhibited. The colour change from black core to red rim in the brick appears to arise from the oxidation state of iron i.e. from Fe3O4 magnetite core to the Fe2O3 hematite outer region. If the firing atmosphere lacks oxygen, no red colour develops and brick material remains in a dark grey colour both inside and outside of the fired refractory brick piece.
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The following factors determine the extent of black core in refractory bricks:
As the name suggests a Black Core is a circular or semi-circular shaped black or gray spots formed around the core or middle portion in fire clay refractory bricks (aluminosilicate refractory bricks mostly containing good percentage of raw clay).
These are not desirable since presence of Black Core spots reduces the normal life of a refractory brick and sometimes, also cause bloating in the furnace.