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Showing posts with label Refractory formulations. Show all posts
Showing posts with label Refractory formulations. Show all posts

The Functions of Silica Fume (Microsilica) and other Ultrafine or Microfine Additives in Refractory Castables

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The unshaped refractories, commonly known as Monolithic refractories are manufactured by suitably blending graded refractory aggregates, binders, fillers & (/or) special additives used for modification of ultimate properties. The refractory aggregates chosen for the formulation of refractory castables have a major contribution in determining their ultimate product quality. Along with this and many other input parameters, especially the high temperature properties of all type of Castables (Aluminous / Basic) depend a lot on the additive’s level and type used. All ingredients, binders, and additives of different chemical compositions and grading are chosen, blended to provide the proper characteristics for various applications of monolithics. 

Effect of Water Addition vs. Ultrafine Additives (Silica Fume) in Castable Refractories


For castable refractories the mobility of various particles is essential for proper placement of the castable. One method to achieve mobility is by adding more water, but this increases porosity & thus affects the performance both at normal & elevated temp. Therefore, addition of water should be minimized. The desired fluidity can be achieved by maintaining the coarser particles separated from one another by suspension of fines and ultrafine additives combined with the state of flocculation within the suspension. The role of the grains of these ‘Microfines or Ultrafine Additives’ can be compared with those of the balls in a ball-bearing.


What are the commonly used Ultrafine Additives in Refractory Castables?


Read: Benefits of using Steel Fibers and Organic Fibers in  Refractory Castables and other Monolithic refractories


The commonly used microfines or ultrafine additives are Silica Fume also known as Microsilica or Fumed Silica, microfine Alumina (Al2O3), ultrafine green Chrome Oxide (Cr2O3) etc. Silica fume is a by-product of producing silicon metal or ferrosilicon alloys. Silica fume consists primarily of amorphous (non-crystalline) silicon dioxide (SiO2). Because of its super fine particles, large surface area, and the high SiO2 content, silica fume is a very reactive.

The addition of Microsilica or Silica Fume has other advantages also, since these micro fine silica particles easily react with alumina present in the material to form Mullite which, in turn, helps in enhancing refractory properties of the product.

The addition of certain percentage of superfine green Chrome Oxide (Cr2O3) in Alumina castables increases the slag corrosion resistance & HMOR of the product significantly because of the formation of Alumina-Chrome (Corundum) solid-solution.

There are several manufacturers of fumed silica. Some well-known global brands of fumed silica are of Elkem Materials, AEROSIL of Evonik Industries, Norchem Concrete Products. 

 

Read: Advantages of using Gel Bond and Colloidal Silica in Monolithic Refractories

Advantages of using Gel Bond and Colloidal Silica in Monolithic Refractories

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5-Jan-2009

What is Gel Bond?

The principle behind this bonding is the formation of a ‘gel’ from a ‘sol’ which surrounds the refractory Aggregates through a network skeleton which, with further heating, develops strength & ultimately goes through sintering to form ceramic bonding. Actually the mechanism is thixotropy, which lies in the fact that some substances, when agitated (under mechanical force), pass from the state of a ‘gel’ to that of a colloidal dispersion ‘sol’ and goes back to the state of a ‘gel’ again when the mechanical forces stop. The phenomenon of thixotropy is based on the theory of dispersion & subsequent flocculation of ultrafine powders. Various sols used in the bonding process e.g. Silica, Alumina, Zircon, and Titania. The incorporation of gel bond in place of conventional binders (High Alumina Refractory Cement) has made it possible to improve the high temperature properties of castable refractories considerably mainly because of the absence of low-melting phases (CA, CA2, C12A7, C2AS, C4AF) and impurities.


Advantages of Gel Bond

Several advantages of the gel-bond compositions compared to LCC & ULCC as have been reported are:

Also Read: The Functions of Silica Fume (Microsilica) and other ultra fine additives in the formulations of Refractory Castables

  • Less mixing time since gel bond formulations do not require other minor additives or deflocculants like the cement containing castables.
  • Shorter drying time and so reduced drying flaws. This is because water is not added or required for mixing.
  • Better refractoriness because of the absence low melting phases like- anorthite or gehlinite.
  • Colloidal silica being more viscous than the water, help to maintain more separation of refractory particles which, in turn, provide better thermal shock resistance.
  • Better chemical resistance.
  • Because of the various superior properties of gel bond castables / pumpables as described above, they yield longer campaign life, less downtime and so reduce cost of furnace operation.
  • Longer shelf life since there is no hydratable phase as in LCC, ULCC.


Applications of Gel Bond Castables / Pumpables (Gel Bond Monolithic Refractories)


Because of Gel bond Castables / Pumpables (Gel bond monolithic refractories) have been found to give better results in terms of both conveniences of applications as well as properties in almost all type of industries:

  • in cement industries - high temperature rotary kiln burning zone, rotary kiln incinerators lining
  • in glass industries - outside the Glass Melting Tank furnace and sidewalls and roofs
  • in Blast furnace trough - because of the better flowability these can be more conveniently installed by a pump with reduced installation time
  • in Torpedo and other transfer Ladles then Tundish back-up lining, Electric furnace Deltas and Runners
  • in secondary operations like - Reheating furnace hearth, roof. The installation of colloidal silica bonded castables / pumpables has shown significant improvement especially in reheating furnace roof areas, both during installation and drying (which has been found to take about 60% less time than the conventional ramming mixes & plastics)
Related Post: Benefits of using Steel Fibers and Organic Fibers in  Refractory Castables and other Monolithic refractories

Colloidal Silica / Silica Sol

Colloidal Silica or Sol or Silica Sol are the different names, consists of a stable dispersion amorphous silica particles. To achieve this, the silica particles must be small enough such that they are largely unaffected by gravity. Therefore, silica particle sizes are usually of the order of less than 100 nanometers. Initially colloidal silica was used in refractories for the purpose of coating in various applications like ingot casting, investment casting etc. It was during late 80’s when for the first time colloidal silica started to be used as bonding agent in monolithic refractories. During late 80’s refractories based on colloidal silica became available in the market in ramming, gunning and castable formulations. The development of gel bond refractories with colloidal silica as the bonding agent has been a major breakthrough in refractory technology. Since the type of colloidal silica used in refractories is available commercially, it became easy for many to take advantage of this technology. In lieu of conventional binders, colloidal silica can be used as bonding agent in all type of monolithic refractories such as castables, ramming and gunning mixes. Its use in castables has given rise to the convenience of refractory applications by pumping, thus providing a considerable advantage over conventional binders. Another big advantage is that unlike calcium aluminate cement bonded refractories; these refractories do not require following specific temperature parameters for drying and hence reduce drying flaws, installation time. Colloidal silica bonded castables / pumpables not only perform better and reduce costs of furnace operation, but also eliminate work place hazards for workers. The nano sized particles of colloidal silica, due to their higher viscosity consistency, maintain uniform inter-particulate distances resulting in increase of the permeability of the mix and hence provide smooth and speedy drying as well as improved reactivity also increasing the castable sinterability, promoting mullite formation. Colloidal silica bonded castables / pumpables can be extensively used in blast furnace cast house refractories (Alumina - Silicon Carbide - Graphite formulations) as well as for all other applications as mentioned above.